Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology
Department
of Chemistry, University of Nebraska—Lincoln, Lincoln, Nebraska 68588-0304, United States
of Chemistry, University of Nebraska—Lincoln, Lincoln, Nebraska 68588-0304, United States
ACS Catal., 2016, 6 (4), pp 2205–2210
DOI: 10.1021/acscatal.6b00175
Publication Date (Web): February 23, 2016
Copyright © 2016 American Chemical Society
*E-mail: jtakacs1@unl.edu.
Abstract
A
new ruthenium complex catalyzes the amination of primary and secondary
alcohols and the regioselective mono- and sequential diamination of
diols via the borrowing hydrogen pathway. Several variations on new
intra- and intermolecular cyclizations of aminoalcohols, diols, and
diamines lead to heterocyclic ring systems.
new ruthenium complex catalyzes the amination of primary and secondary
alcohols and the regioselective mono- and sequential diamination of
diols via the borrowing hydrogen pathway. Several variations on new
intra- and intermolecular cyclizations of aminoalcohols, diols, and
diamines lead to heterocyclic ring systems.
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