† Laboratoire
de Chimie de Coordination, Centre National
de la Recherche Scientifique UPR 8241, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
de Chimie de Coordination, Centre National
de la Recherche Scientifique UPR 8241, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France
‡ Laboratoire
Hétérochimie Fondamentale et Appliquée, Université de Toulouse 3 Paul Sabatier, UPS
and CNRS UMR 5069, 118
Route de Narbonne, F-31062 Toulouse Cedex 9, France
Hétérochimie Fondamentale et Appliquée, Université de Toulouse 3 Paul Sabatier, UPS
and CNRS UMR 5069, 118
Route de Narbonne, F-31062 Toulouse Cedex 9, France
ACS Catal., 2016, 6, pp 3537–3552
DOI: 10.1021/acscatal.6b00684
Publication Date (Web): April 26, 2016
Copyright © 2016 American Chemical Society
*E-mail: daniel.pla@cantab.net. Phone: +33581314123., *E-mail: gomez@chimie.ups-tlse.fr. Phone: +33561557738.
Abstract
The
past decade has seen the development of a new reactivity concept,
exploiting the ubiquity of C–H bonds. The direct activation of this bond
type brings forth a straightforward way for the derivatization of
organic molecules. Consequently, the design of metal catalyzed C–H bond
functionalization reactions has become a flourishing area in organic
synthesis. Thus, this review focuses on molecular transformation of
“unactivated” C(sp3)–H and C(sp2)–H bonds present
in feedstock and readily available hydrocarbons into valuable chemicals
by nanoparticle-leveraged C–H activation, resulting in more sustainable
approaches for industrial applications. The distinctive reactivity
properties of these nanoentities lead to remarkable reactivity
specificities depending on the type of surface sites and the structure
dynamics, directly impacting the process selectivity.
past decade has seen the development of a new reactivity concept,
exploiting the ubiquity of C–H bonds. The direct activation of this bond
type brings forth a straightforward way for the derivatization of
organic molecules. Consequently, the design of metal catalyzed C–H bond
functionalization reactions has become a flourishing area in organic
synthesis. Thus, this review focuses on molecular transformation of
“unactivated” C(sp3)–H and C(sp2)–H bonds present
in feedstock and readily available hydrocarbons into valuable chemicals
by nanoparticle-leveraged C–H activation, resulting in more sustainable
approaches for industrial applications. The distinctive reactivity
properties of these nanoentities lead to remarkable reactivity
specificities depending on the type of surface sites and the structure
dynamics, directly impacting the process selectivity.
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